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· Chemical Engineering Online
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Keele University researchers report a low-voltage, membrane-free alkaline electrolyzer that pairs hydrogen generation at the cathode with oxidation of 5‑hydroxymethylfurfural (HMF) to 2,5‑furandicarboxylic acid (FDCA) at the anode. By replacing the typical oxygen-evolution reaction with FDCA electrosynthesis, the setup co-produces green hydrogen and a high-value bioplastic precursor, potentially reducing energy use and eliminating the need for a membrane.

What do you see as the biggest opportunities and scale-up challenges for membrane-free, paired electrolysis that co-produces hydrogen and FDCA (e.g., HMF feedstock availability, catalyst durability, or product separation)?

Low-voltage, membrane-free electrolysis produces hydrogen and FDCA

This article was originally posted on chemengonline.com.

A new approach to the traditional alkaline electrolyzers used to produce “green” hydrogen from water eliminates the membrane and introduces a new reaction mechanism at the anode, enabling the production of a high-value plastic precursor, 2,5-furandicarboxylic acid (FDCA). Developed at Keele University, the new electrolyzer facilitates two different chemical reactions — the conventional conversion of water into hydrogen at the cathode; and the electrosynthesis of 5-hydroxymethylfurfural (HMF) into FDCA at the anode.

The post Low-voltage, membrane-free electrolysis produces hydrogen and FDCA appeared first on Chemical Engineering.

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